Robust Electron Transport Layers via In Situ Cross-Linking of Perylene Diimide and Fullerene for Perovskite Solar Cells

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dc.contributor.authorYum, J. H.
dc.contributor.authorMoon, S. J.
dc.contributor.authorYao, L.
dc.contributor.authorCaretti, M.
dc.contributor.authorNicolay, S.
dc.contributor.authorKim, D. H.
dc.contributor.authoret al.
dc.date.accessioned2021-12-09T14:04:26Z
dc.date.available2021-12-09T14:04:26Z
dc.date.issued2019
dc.description.abstractWhile employing charge transport layers (CTLs) in optoelectronic devices including hybrid perovskite solar cells is essential for high performance, using solution-processed organic semiconductor-based CTLs poses challenges for device fabrication. Cross-linking the organic semiconductor is a viable approach, but cross-linked CTLs require additional development for practical application. Here a facile in situ strategy to prepare a cross-linked electron transport layer (ETL) is demonstrated by employing a semiconducting cross-linker composed of perylenediimidediazide, together with the fullerene (C-60) derivative coded as PCBM. Varying the PCBM ratio the cross-linking conditions affords a tunable ETL that exhibits solvent tolerance, suitable electron mobility (>10(-4) cm(2) V-1 s(-1)), and hydrophobicity at cross-linking temperatures as low as 120 degrees C. In both the n-i-p structure and the p-i-n perovskite solar cells employing our ETL, stable power generation and hysteresis-free performance are achieved. Optimized p-i-n devices with our cross-linked ETL gave power conversion efficiency of over 12% (active area of 1.07 cm(2)). These results suggest that robust n-type semiconducting films obtained with our cross-linking method are promising as ETLs in practical optoelectronic applications.
dc.identifier.citationAcs Applied Energy Materials, vol. 2 (9), pp. 6616-6623, Sep 2019.
dc.identifier.doihttps://doi.org/10.1021/acsaem.9b01154
dc.identifier.urihttps://hdl.handle.net/20.500.12839/362
dc.subjectelectron transport layer, cross-linking, perylene diimide, halide, perovskite, solar cells, high-performance, efficient, hysteresis, films, Materials Science
dc.titleRobust Electron Transport Layers via In Situ Cross-Linking of Perylene Diimide and Fullerene for Perovskite Solar Cells
dc.typeJournal Article
dc.type.csemdivisionsBU-V
dc.type.csemresearchareasSolar Cells and Modules
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